Structure cristalline du tétramétaphosphate de nickel-ammonium heptahydraté: Ni(NH4)2P4O12 · 7H2O
Identifieur interne : 000603 ( France/Analysis ); précédent : 000602; suivant : 000604Structure cristalline du tétramétaphosphate de nickel-ammonium heptahydraté: Ni(NH4)2P4O12 · 7H2O
Auteurs : Amor Jouini [France] ; M. Dabbabi [France] ; A. Durif [France]Source :
- Journal of Solid State Chemistry [ 0022-4596 ] ; 1985.
Abstract
Nickel-ammonium tetrametaphosphate, Ni(NH4)2P4O12 · 7H2O is triclinic with a = 13.841(3); b = 9.621(5); c = 7.482(2)Å; α = 98.05(4); β = 97.25(4); γ = 103.01(4)°; M = 536.59; V = 947.9Å3; Z = 2; Dx = 1.879 g cm−3; μ = 14.524 cm−1, and space group P1. The crystal structure was solved using 1661 independent reflections measured on a single-crystal diffractometer (MoKα). The final R value is 0.056. The two crystallographic independent nickel atoms Ni(1) and Ni(2) are octahedrally coordinated: Ni(1) by four oxygen atoms and two water molecules, Ni(2) by six water molecules. Ni(1), closely connected to two P4O12 rings, forms a complex anion [Ni(P4O12)2(H2O)2]6− which is associated to ammonium polyhedra and [Ni(H2O)6]2+ octahedra. Another interesting feature of this atomic arrangement is the presence of a large channel (10 × 4) Å2 parallel to the c axis. The internal surface of this channel is covered by six zeolitic water molecules.
Url:
DOI: 10.1016/0022-4596(85)90157-4
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000629
- to stream Istex, to step Curation: 000340
- to stream Istex, to step Checkpoint: 000D08
- to stream Main, to step Merge: 001513
- to stream Main, to step Curation: 001444
- to stream Main, to step Exploration: 001444
- to stream France, to step Extraction: 000603
Links to Exploration step
ISTEX:1D39231AE98ED21580B63610B89F93B4E5BC91ACLe document en format XML
<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Structure cristalline du tétramétaphosphate de nickel-ammonium heptahydraté: Ni(NH4)2P4O12 · 7H2O</title>
<author><name sortKey="Jouini, A" sort="Jouini, A" uniqKey="Jouini A" first="A." last="Jouini">Amor Jouini</name>
<affiliation><country>Tunisie</country>
<placeName><settlement type="city">Monastir</settlement>
<region type="region" nuts="2">Gouvernorat de Monastir</region>
</placeName>
<orgName type="university" n="3">Université de Monastir</orgName>
</affiliation>
</author>
<author><name sortKey="Dabbabi, M" sort="Dabbabi, M" uniqKey="Dabbabi M" first="M." last="Dabbabi">M. Dabbabi</name>
</author>
<author><name sortKey="Durif, A" sort="Durif, A" uniqKey="Durif A" first="A." last="Durif">A. Durif</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:1D39231AE98ED21580B63610B89F93B4E5BC91AC</idno>
<date when="1985" year="1985">1985</date>
<idno type="doi">10.1016/0022-4596(85)90157-4</idno>
<idno type="url">https://api.istex.fr/document/1D39231AE98ED21580B63610B89F93B4E5BC91AC/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">000629</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">000629</idno>
<idno type="wicri:Area/Istex/Curation">000340</idno>
<idno type="wicri:Area/Istex/Checkpoint">000D08</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000D08</idno>
<idno type="wicri:doubleKey">0022-4596:1985:Jouini A:structure:cristalline:du</idno>
<idno type="wicri:Area/Main/Merge">001513</idno>
<idno type="wicri:Area/Main/Curation">001444</idno>
<idno type="wicri:Area/Main/Exploration">001444</idno>
<idno type="wicri:Area/France/Extraction">000603</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a">Structure cristalline du tétramétaphosphate de nickel-ammonium heptahydraté: Ni(NH4)2P4O12 · 7H2O</title>
<author><name sortKey="Jouini, A" sort="Jouini, A" uniqKey="Jouini A" first="A." last="Jouini">Amor Jouini</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de chimie minérale, Département de chimie, Faculté des Sciences et Techniques de Monastir, 5000, Monastir, Tunisie</wicri:regionArea>
<wicri:noRegion>Tunisie</wicri:noRegion>
<wicri:noRegion>Tunisie</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Dabbabi, M" sort="Dabbabi, M" uniqKey="Dabbabi M" first="M." last="Dabbabi">M. Dabbabi</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de chimie minérale, Département de chimie, Faculté des Sciences et Techniques de Monastir, 5000, Monastir, Tunisie</wicri:regionArea>
<wicri:noRegion>Tunisie</wicri:noRegion>
<wicri:noRegion>Tunisie</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Durif, A" sort="Durif, A" uniqKey="Durif A" first="A." last="Durif">A. Durif</name>
<affiliation wicri:level="1"><country xml:lang="fr">France</country>
<wicri:regionArea>Laboratoire de cristallographie, Centre National de la Recherche Scientifique, Laboratoire associéà l'Université Scientifique et Médicale de Grenoble, B.P. 166 X 38042 Grenoble, Cédex</wicri:regionArea>
<wicri:noRegion>Cédex</wicri:noRegion>
<wicri:noRegion>Cédex</wicri:noRegion>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Journal of Solid State Chemistry</title>
<title level="j" type="abbrev">YJSSC</title>
<idno type="ISSN">0022-4596</idno>
<imprint><publisher>ELSEVIER</publisher>
<date type="published" when="1985">1985</date>
<biblScope unit="volume">60</biblScope>
<biblScope unit="issue">1</biblScope>
<biblScope unit="page" from="6">6</biblScope>
<biblScope unit="page" to="12">12</biblScope>
</imprint>
<idno type="ISSN">0022-4596</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">0022-4596</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass></textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">Nickel-ammonium tetrametaphosphate, Ni(NH4)2P4O12 · 7H2O is triclinic with a = 13.841(3); b = 9.621(5); c = 7.482(2)Å; α = 98.05(4); β = 97.25(4); γ = 103.01(4)°; M = 536.59; V = 947.9Å3; Z = 2; Dx = 1.879 g cm−3; μ = 14.524 cm−1, and space group P1. The crystal structure was solved using 1661 independent reflections measured on a single-crystal diffractometer (MoKα). The final R value is 0.056. The two crystallographic independent nickel atoms Ni(1) and Ni(2) are octahedrally coordinated: Ni(1) by four oxygen atoms and two water molecules, Ni(2) by six water molecules. Ni(1), closely connected to two P4O12 rings, forms a complex anion [Ni(P4O12)2(H2O)2]6− which is associated to ammonium polyhedra and [Ni(H2O)6]2+ octahedra. Another interesting feature of this atomic arrangement is the presence of a large channel (10 × 4) Å2 parallel to the c axis. The internal surface of this channel is covered by six zeolitic water molecules.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
</country>
</list>
<tree><country name="France"><noRegion><name sortKey="Jouini, A" sort="Jouini, A" uniqKey="Jouini A" first="A." last="Jouini">Amor Jouini</name>
</noRegion>
<name sortKey="Dabbabi, M" sort="Dabbabi, M" uniqKey="Dabbabi M" first="M." last="Dabbabi">M. Dabbabi</name>
<name sortKey="Durif, A" sort="Durif, A" uniqKey="Durif A" first="A." last="Durif">A. Durif</name>
</country>
</tree>
</affiliations>
</record>
Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=$WICRI_ROOT/Wicri/Terre/explor/NickelMaghrebV1/Data/France/Analysis
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000603 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/France/Analysis/biblio.hfd -nk 000603 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien |wiki= Wicri/Terre |area= NickelMaghrebV1 |flux= France |étape= Analysis |type= RBID |clé= ISTEX:1D39231AE98ED21580B63610B89F93B4E5BC91AC |texte= Structure cristalline du tétramétaphosphate de nickel-ammonium heptahydraté: Ni(NH4)2P4O12 · 7H2O }}
This area was generated with Dilib version V0.6.27. |